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D-Camphorsulfonic Acid CAS 3144-16-9

The optically active L- and D-camphorsulfonic acids are important chiral isomer separation agents. The D-isomer can be obtained from natural camphor via bromination and sulfonation, or from racemic camphorsulfonic acid through induced crystallization. Preparation


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Model:
3144-16-9
Brand:
bosschemical
Code:
3144-16-9

Product Description

(1S)-(+)-Camphor-10-sulphonic acid Basic information
Synthesis
Product Name:	(1S)-(+)-Camphor-10-sulphonic acid
CAS:	3144-16-9
MF:	C10H16O4S
MW:	232.3
EINECS:	221-554-1
Mol File:	3144-16-9.mol
(1S)-(+)-Camphor-10-sulphonic acid Chemical Properties
Melting point	196-200 °C (dec.)(lit.)
alpha	22 º (589nm, c=20, H2O 25 ºC)
Boiling point	344.46°C (rough estimate)
density	1.2981 (rough estimate)
refractive index	21.5 ° (C=5, H2O)
storage temp.	Store below +30°C.
solubility	Exhibit moderate solubility in HCCl.
pka	1.17±0.50(Predicted)
form	Crystalline Powder
color	White to off-white
PH	0.3 (200g/l, H2O)
Optical Rotation	[α]20/D +21.5±1°, c = 10% in H2O
biological source	human
Water Solubility	SOLUBLE
Sensitive	Hygroscopic
Merck	141,734
BRN	2809675
Stability:	Stable. Protect from moisture. Incompatible with strong oxidizing agents, strong bases.
InChI	1S/C10H16O4S/c1-9(2)7-3-4-10(9,8(11)5-7)6-15(12,13)14/h7H,3-6H2,1-2H3,(H,12,13,14)/t7-,10-/m1/s1
InChIKey	MIOPJNTWMNEORI-GMSGAONNSA-N
SMILES	[H][C@@]12CC[C@@](CS(O)(=O)=O)(C(=O)C1)C2(C)C
CAS DataBase Reference	3144-16-9(CAS DataBase Reference)
EPA Substance Registry System	Bicyclo[2.2.1]heptane-1-methanesulfonic acid, 7,7-dimethyl-2-oxo-, (1S,4R)- (3144-16-9)