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Trimethylsulfoxonium Bromide CAS 25596-24-1

Trimethylsulfoxonium bromide is an organic sulfur compound with the chemical formula (CH₃)₃SOBr. It appears as a white to off-white crystalline solid, with a faint characteristic odor. Soluble in water and polar organic solvents such as dimethyl sulfoxide (DMSO) and dimethylformamide (DMF). Commonly used as a reagent for the generation of dimethyloxosulfonium methylide, a useful intermediate for methylenation reactions (the conversion of carbonyl compounds to epoxides or alkenes). Also functions as a phase-transfer catalyst and as a reactant in the synthesis of various heterocyclic compounds. Stable under normal storage conditions but hygroscopic; should be kept in tightly sealed containers away from moisture.
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TRIMETHYLSULFOXONIUM BROMIDE Basic information

Product Name:

TRIMETHYLSULFOXONIUM BROMIDE

CAS:

25596-24-1

MF:

C3H9BrOS

MW:

173.07

EINECS:

251-228-4

Mol File:

25596-24-1.mol

TRIMETHYLSULFOXONIUM BROMIDE Chemical Properties

density

1.440 (estimate)

storage temp.

Inert atmosphere,Room Temperature

form

powder to crystal

color

White to Almost white

InChI

InChI=1S/C3H9OS.BrH/c1-5(2,3)4;/h1-3H3;1H/q+1;/p-1

InChIKey

KEPJZBFFLDRKSF-UHFFFAOYSA-M

SMILES

[S+](=O)(C)(C)C.[Br-]

CAS DataBase Reference

25596-24-1

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