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Polymethylene polyphenyl polyisocyanate CAS 9016-87-9

Polyaniline polyisocyanate (PAPI), commonly known as polymerized MDI or crude MDI, CAS 9016-87-9, is a light yellow to brown viscous liquid typically composed of about 50% diphenylmethane diisocyanate (MDI) mixed with 50% higher functional polyisocyanates. It is a key raw material for producing polyurethane rigid foam, widely used in the insulation layer of refrigerators, pipes, and building panels. At the same time, it also has important applications in adhesives, coatings, sealants, and other fields.
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Polymethylene polyphenyl polyisocyanate Basic information

Product Name:

Polymethylene polyphenyl polyisocyanate

CAS:

9016-87-9

MF:

C8H7NO2

MW:

149.14668

EINECS:

922-627-7

Mol File:

9016-87-9.mol

Polymethylene polyphenyl polyisocyanate Chemical Properties

Boiling point

392 °C5 mm Hg

density

1.2 g/mL at 25 °C(lit.)

vapor density

8.6 (vs air)

refractive index

n20/D 1.634

Fp

>230 °F

storage temp.

Refrigerator, Under inert atmosphere

solubility

DMSO (Sparingly), Ethyl Acetate (Slightly), Methanol (Soluble)

form

Oil

color

Yellow to Orange

Specific Activity

~3.2isocyanate groups/molecule

Stability:

Stable. Incompatible with strong oxidizing agents, alcohols. May decompose in moist air, or on contact with water.

InChI

InChI=1S/C7H5NO.CH2O/c9-6-8-7-4-2-1-3-5-7;1-2/h1-5H;1H2

InChIKey

JTEOXXUIKUHXLD-UHFFFAOYSA-N

SMILES

O=C=NC1C([H])=C([H])C([H])=C([H])C=1[H].O=C([H])[H]

IARC

3 (Vol. 19, Sup 7) 1987

EPA Substance Registry System

Polymeric diphenylmethane diisocyanate (9016-87-9)

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Chemical detection methods

  • Spectroscopic Analysis Methods

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  • Mass Spectrometry Analysis

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    ICP-MS: Trace Metal Elements (ppb Level)
    TOF-MS: Precise Molecular Weight Determination

  • Electrochemical analysis methods
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    Polarographic methods / Voltammetric methods
    Coulometric analysis
  • Thermal Analysis Methods
    Thermogravimetric Analysis (TGA)
    Differential Scanning Calorimetry (DSC)
    Differential Thermal Analysis (DTA)
  • Classical wet chemical analysis
    Titration analysis
    Gravity analysis
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