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LiF Lithium fluoride CAS 7789-24-4

Lithium fluoride is a white powder with a sodium chloride crystal structure. Relative density 2.640, melting point 848 ℃, boiling point 1673 ℃. It begins to evaporate at 1100-1200 ℃, and its vapor is alkaline. Lithium fluoride is slightly soluble in water, but difficult to dissolve in alcohol and other organic solvents. At room temperature, lithium fluoride is easily soluble in nitric acid and sulfuric acid, but insoluble in hydrochloric acid. It can form Li2HF acid salts with hydrofluoric acid.
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  • 7789-24-4

  • bosschem

  • 7789-24-4

Lithium fluoride (LiF)

CAS 7789-24-4

Alais: Lithium monofluoride

Molecular formula: FLi

Molecular weight: 25.94

Structural formula:

5e1e9132691c92ab54bc410f9c84b3c3_7789-24-4

1.Performance and use

Lithium fluoride is a white powder with a sodium chloride crystal structure. Relative density 2.640, melting point 848 ℃, boiling point 1673 ℃. It begins to evaporate at 1100-1200 ℃, and its vapor is alkaline. Lithium fluoride is slightly soluble in water, but difficult to dissolve in alcohol and other organic solvents. At room temperature, lithium fluoride is easily soluble in nitric acid and sulfuric acid, but insoluble in hydrochloric acid. It can form Li2HF acid salts with hydrofluoric acid.

1: Mainly used in the ceramic industry

2: Widely used in the manufacturing of welding rods, prisms for spectrometers and X-ray monochromators, carriers for proliferation reactions, and lithium-ion battery manufacturing.


2. Technical indicators


Product Name: Lithium fluoride
CAS: 7789-24-4
MF: FLi
MW: 25.94
EINECS: 232-152-0
Mol File: 7789-24-4.mol
Lithium fluoride Chemical Properties
Melting point 845 °C (lit.)
Boiling point 1681 °C
density 2.64 g/mL at 25 °C (lit.)
vapor pressure 0Pa at 25℃
refractive index 1.3915
Fp 1680°C
storage temp. Store at +5°C to +30°C.
solubility Soluble in 0.29 g/100 mL (20°C) and hydrogen fluoride. Insoluble in alcohol.
form random crystals
color White to off-white
Specific Gravity 2.635
PH 6.0-8.5 (25℃, 0.01M in H2O)
Water Solubility 0.29 g/100 mL (20 ºC)
Sensitive Hygroscopic
λmax λ: 260 nm Amax: ≤0.01
λ: 280 nm Amax: ≤0.01
Merck 145,531
Solubility Product Constant (Ksp) pKsp: 2.74
Exposure limits ACGIH: TWA 2.5 mg/m3
NIOSH: IDLH 250 mg/m3; TWA 2.5 mg/m3
Stability: Stable, but hygroscopic. Hydrolyzes in the presence of water to form hydrofluoric acid, which attacks glass - do not store in glass bottles. Incompatible with aqueous solutions, strong acids, strong oxidizing agents.
InChIKey PQXKHYXIUOZZFA-UHFFFAOYSA-M
LogP 0.23 at 25℃
CAS DataBase Reference 7789-24-4(CAS DataBase Reference)
NIST Chemistry Reference Lithium fluoride(7789-24-4)
EPA Substance Registry System Lithium fluoride (7789-24-4)



composition

standard

/ reqiured ( % )

Analysis

LiF

≥99.0

99.16

Fe

≤0.01

0.0024

Ca

≤0.1

0.036

H2O

≤0.1

0.046

Na+K

≤0.05

0.029

SO42-

≤0.05

0.024

SiO2

≤0.1

0.024

3. Packaging and storage

Package : 25kg/bag 

Storage : Store at +5°C to +30°C.

4. Related keywords  

Lithium fluoride

CAS 7789-24-4

Battery

LiF

lithium fluoride uses

lif lithium fluoride

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