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Hydroxypropyl acrylate CAS 25584-83-2

Hydroxypropyl Acrylate (HPA) is a functional acrylate monomer containing both acrylate and hydroxyl functional groups, allowing it to participate in both free-radical polymerization and subsequent chemical reactions such as crosslinking. It is a clear, colorless to light yellow liquid with a characteristic ester odor.

Due to its dual functionality, Hydroxypropyl Acrylate is widely used in coatings, adhesives, sealants, and elastomers. It enhances adhesion, flexibility, chemical resistance, and durability of the final polymer product. It can copolymerize with other acrylates, methacrylates, and vinyl monomers, making it a versatile building block in polymer chemistry.

Its hydroxyl group provides a site for further crosslinking reactions with isocyanates, melamine-formaldehyde resins, or epoxy compounds, contributing to improved mechanical and chemical properties.
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  • 25584-83-2

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  • 25584-83-2

Product name: Hydroxypropyl Acrylate
English alias: HPA; 2-Hydroxypropyl acrylate
CAS: 25584-83-2
Molecular formula: C6H10O3
Appearance: Colorless to light yellow transparent liquid
Package: 25kg/drum

What is Hydroxypropyl Acrylate?

Hydroxypropyl Acrylate (HPA) is a functional acrylate monomer containing both acrylate and hydroxyl functional groups, allowing it to participate in both free-radical polymerization and subsequent chemical reactions such as crosslinking. It is a clear, colorless to light yellow liquid with a characteristic ester odor.

Due to its dual functionality, Hydroxypropyl Acrylate is widely used in coatings, adhesives, sealants, and elastomers. It enhances adhesion, flexibility, chemical resistance, and durability of the final polymer product. It can copolymerize with other acrylates, methacrylates, and vinyl monomers, making it a versatile building block in polymer chemistry.

Its hydroxyl group provides a site for further crosslinking reactions with isocyanates, melamine-formaldehyde resins, or epoxy compounds, contributing to improved mechanical and chemical properties.

COA

Item

Specification

Result

Appearance

Clear liquid

Clear liquid

Purity (%)

≥ 96.0

97.6

Water content (%)

≤ 0.3

0.12

Inhibitor (MEHQ ppm)

200 ± 20

205

Acid value (mgKOH/g)

≤ 1.0

0.5

Conclusion


PASS

Application:

Acrylic coatings – Used in waterborne and solvent-based systems to improve adhesion, flexibility, and UV resistance
Adhesives and sealants – Enhances bonding strength and moisture resistance
Photopolymer resins – Suitable for UV-curable systems, including 3D printing materials and printing inks
Textile finishing agents – Imparts softness, elasticity, and resistance to washing
Plastic and rubber modifiers – Used to improve compatibility, crosslink density, and performance in elastomeric products
Reactive diluent – Acts as a viscosity reducer while maintaining reactivity in various monomer or oligomer systems

Safety Profile:

Hydroxypropyl Acrylate is a moderately hazardous chemical and may cause skin and eye irritation. It should be handled with appropriate personal protective equipment. Prolonged exposure may cause allergic skin reactions. Ensure adequate ventilation during use. Avoid inhalation or contact with skin and eyes.

Hazard Class: Irritant
Handling Recommendations: Use gloves, goggles, and protective clothing
Disposal: Dispose of contents/container in accordance with local/regional regulations

Storage Requirements:

Store in a cool, dry, well-ventilated area
Keep container tightly closed
Avoid direct sunlight and ignition sources
Storage temperature: 5–35°C
Add inhibitors (e.g., MEHQ) to prevent polymerization during storage

Transport & Packaging:

Hydroxypropyl Acrylate is supplied in sealed packaging of different sizes. It is typically available in:
25 kg drums
200 kg steel drums
1000 kg IBC tanks

Ensure transportation complies with local hazardous goods regulations. Protect against heat, sunlight, and physical damage during transport.

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Chemical detection methods

  • Spectroscopic Analysis Methods

    Ultraviolet-Vis Spectrophotometry (UV-Vis)
    Infrared Spectroscopy (IR/FTIR)
    Atomic Absorption Spectroscopy (AAS)
    X-ray Fluorescence Spectroscopy (XRF)
    Nuclear Magnetic Resonance Spectroscopy (NMR)

  • Chromatographic Analysis

    Gas Chromatography (GC)
    High Performance Liquid Chromatography (HPLC)
    Ion Chromatography (IC)
    Thin Layer Chromatography (TLC)

  • Mass Spectrometry Analysis

    GC-MS / LC-MS/MS: Qualitative and Quantitative Analysis
    ICP-MS: Trace Metal Elements (ppb Level)
    TOF-MS: Precise Molecular Weight Determination

  • Electrochemical analysis methods
    Polypotentiometric methods
    Conductivity methods
    Polarographic methods / Voltammetric methods
    Coulometric analysis
  • Thermal Analysis Methods
    Thermogravimetric Analysis (TGA)
    Differential Scanning Calorimetry (DSC)
    Differential Thermal Analysis (DTA)
  • Classical wet chemical analysis
    Titration analysis
    Gravity analysis
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