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Trimethyl Borate CAS 121-43-7

Trimethyl borate is an organoboron compound with the chemical formula B(OCH₃)₃. It appears as a colorless liquid with a pungent, sweet, ester-like odor. Reacts with water (hydrolyzes), but soluble in organic solvents such as methanol, ethanol, diethyl ether, and tetrahydrofuran. Commonly used as a reagent in organic synthesis for the preparation of boronic esters and as a source of boric acid in various chemical reactions. Also functions as a flame retardant additive, a crosslinking agent in polymer and resin formulations, and as a precursor for the chemical vapor deposition of boron-containing films. Highly moisture-sensitive; should be stored in tightly sealed containers away from water and humidity.
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  • 121-43-7

  • Boss Chemical

  • 121-43-7

Trimethyl borate Basic information

Product Name:

Trimethyl borate

CAS:

121-43-7

MF:

C3H9BO3

MW:

103.91

EINECS:

204-468-9

Mol File:

121-43-7.mol

Trimethyl borate Chemical Properties

Melting point

-34 °C (lit.)

Boiling point

68-69 °C (lit.)

density

0.932 g/mL at 20 °C (lit.)

vapor density

3.59 (vs air)

vapor pressure

147.9-148 hPa ( 20 °C)

refractive index

n20/D 1.358(lit.)

Fp

8 °F

storage temp.

Store at <= 20°C.

solubility

Miscible with tetrahydrofuran, ether, isoporpylamine, hexane and methanol.

form

Liquid

Specific Gravity

0.915

color

Colorless

Water Solubility

reacts

Sensitive

Moisture Sensitive

Hydrolytic Sensitivity

7: reacts slowly with moisture/water

Merck

149,712

BRN

1697939

Dielectric constant

8.2(20℃)

Exposure limits

ACGIH: TWA 200 ppm; STEL 250 ppm (Skin)

OSHA: TWA 200 ppm(260 mg/m3)

NIOSH: IDLH 6000 ppm; TWA 200 ppm(260 mg/m3); STEL 250 ppm(325 mg/m3)

Stability:

Stable. Incompatible with oxidizing agents. Decomposes slowly in the presence of moisture, rapidly in water. Flammable.

InChI

1S/C3H9BO3/c1-5-4(6-2)7-3/h1-3H3

InChIKey

WRECIMRULFAWHA-UHFFFAOYSA-N

SMILES

COB(OC)OC

CAS DataBase Reference

121-43-7(CAS DataBase Reference)

NIST Chemistry Reference

Boric acid, trimethyl ester(121-43-7)

EPA Substance Registry System

Boric acid (H3BO3), trimethyl ester (121-43-7)

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